U . S . Patent Jun . 27 ,

The present invention relates to a nitrogen adsorbent having nitrogen selective adsorptivity by including an organic inorganic hybrid nanoporous material having a coordina tively unsaturated metal site with density of 0.2 mmol/g to 10 mmol/g in a skeleton, Surface or pore; and use thereof, Such as a device separating nitrogen from a gas mixture containing nitrogen and methane, a pressure Swing adsorp tion separation device and a temperature Swing adsorption separation device for separating nitrogen provided, a method for separating nitrogen and methane from a gas mixture containing nitrogen and methane, a device for separating nitrogen, oxygen or argon, a method for separating nitrogen, oxygen or argon from a gas mixture containing nitrogen, oxygen or argon, and a method for preparing nitrogen or (Continued)